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primary topic: Exploring Mn+/Silicalite-1 As A Catalyst For Biginelli Reaction To Produce Dihydropyrimidinone Derivatives

Exploring Mn+/Silicalite-1 As A Catalyst For Biginelli Reaction To Produce Dihydropyrimidinone Derivatives
type: AcademicArticle
type: Article
abstract: A series of Mn+/silicalite-1 was prepared to be used as a Lewis acid heterogeneous catalyst for a one-pot multicomponent Biginelli reaction. The catalysts were characterized by FTIR, XRD, NH3-TPD, and BET. The mesoporous catalysts possess a pore diameter of 13.83 nm (138.3 Å), a surface area of 282.43 m2/g, and a pore volume of 0.98 cm3/g, which can facilitate the transport of reactants and products smoothly during the catalytic process. Besides the acidity of the catalyst, the maximum temperature of NH3-desorption plays an important role in the catalytic activity. Cr3+/silicalite-1 showed the most active catalyst, while Zn2+/silicalite-1 showed the most selective one. Besides DHPM derivatives as a major Biginelli product, C6-styril of DHPM and Knoevenagel products were isolated if the reaction was conducted using Cr3+/- and Fe3+/silicalite-1. Catalyst Cr3+/silicalite-1 can be used to produce DHPM attaching various substituents and showed a green catalyst potential due to its reusability capacity
volume: 17
issue: 4
is part of: Rasayan J. Chem
status: peerReviewed
status: published
author list: authors
creator: Hin Taufiq-Yap Y. Hin
type: EPrint
type: ArticleEPrint
is part of: repository
has document: Exploring Mn+/Silicalite-1 As A Catalyst For Biginelli Reaction To Produce Dihydropyrimidinone Derivatives (Text)
subject: QD Chemistry

Exploring Mn+/Silicalite-1 As A Catalyst For Biginelli Reaction To Produce Dihydropyrimidinone Derivatives (Text)
type: Document
has file: LIT 2024 September Hery Suwito, Lutfan Zulianto, Kautsar Ul Haq, Abdulloh Abdulloh, Erwanto Erwanto, Fitria Pebriani, Arjun N. Jihadi Al.pdf
has part: LIT 2024 September Hery Suwito, Lutfan Zulianto, Kautsar Ul Haq, Abdulloh Abdulloh, Erwanto Erwanto, Fitria Pebriani, Arjun N. Jihadi Al.pdf

Rasayan J. Chem
type: Organization

Rasayan J. Chem
type: Collection
issn: 09760083

Hin Taufiq-Yap Y. Hin
type: Person
given name: Hin
family name: Taufiq-Yap Y. Hin

Suwito Hery Suwito
type: Person
given name: Suwito
family name: Hery Suwito

Erwanto Erwanto
type: Person
given name: Erwanto
family name: Erwanto

Universitas Bojonegoro
type: Organization

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primary topic: Exploring Mn+/Silicalite-1 As A Catalyst For Biginelli Reaction To Produce Dihydropyrimidinone Derivatives

QD Chemistry
type: Concept